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III-V Materials

HV Overview of Research

The work on III-V materials can be broken down into three main research themes:
  • electrical isolation of III-V semiconductor materials using ion implantation
  • SMARTCUT in GaAs

Aims and Objectives

Aims:
  • to gain a detailed physical understanding of the electrical isolation of III-V semiconductor materials using ion implantation. 
  • to examine the SMARTCUT technique in gallium arsenide.
Objectives:

Electrical Isolation in III-V Materials using ion implantation
  • to use the data obtained from fundamental measurements to optimise present techniques used for isolation.
  • to develop technology to enable implant isolation to be expanded to the fabrication of devices for which no reliable method currently exists.
  • to offer any newly developed technology to users of the IBC, including industry.
SMARTCUT in GaAs
  • to understand the mechanisms for the production of blisters in hydrogen implanted GaAs.

Achievementsdisplay

Electrical Isolation in III-V Materials using ion implantation:

  • shown that 200°C implants of protons in GaAs produce high sheet resistances (108 ohms/square) with improved thermal stability compared with room temperature implants.
  • developed technology to produce sheet resistances of about 107 ohms/square for both n-type and p-type InP and InGaAs.
  • industry using our improved technology for producing microwave devices/circuits.
  • work has been in collaboration with UCL and UMIST and includes the industrial partners, PRP Optoelectronics, Qinetiq and E2V Technologies.

SMARTCUT in GaAs:
  • have produced blisters in GaAs following implantation at 200°C without subsequent annealing.
  • have produced blisters in 300°C implants in GaAs, but only after annealing.
  • have measured damage and hydrogen profiles using RBS and ERD.
  • have found that the formation of blisters depends critically on the substrate temperature and the dose rate.
  • collaboration has been established with UCLA and Salford.
Update

This work, which has mostly been supported by an EPSRC funded project, has continued to make good progress within the last year. Recently we have developed techniques to produce resistivities of about 107 ohm/square for both n-type and p-type InP and InGaAs, which is better than has ever been achieved before. We have studied a wide range of ion species and ion doses as a function of the implant temperature, the material type and the doping density and have applied many of our findings to real devices, such as quantum well saturable absorbers and HBTs. All of our results have been communicated to our industrial collaborators and many have been published (>30 publications); for further details see the project website .  

A second small grant was awarded by EPSRC to support additional ion beam hours required to complete the project. Another small grant application has been made to support work begun on GaInAsP.

A new topic, SMARTCUT of GaAs has been running for about one year in which an EPSRC sponsored student is studying the basics of the process. We have established a collaboration with groups from UCLA and Salford.


Recent Publications (2002 -2004)

For a full list of IBC publications please click here .

  1. S Ahmed, BJ Sealy and RM Gwilliam, Annealing characteristics of the implant isolated n-type GaAs layers: effects of ion species and implant temperature, NIM B 206 (2003) 1008-1012.
  2. P Too, S Ahmed, R Jakiela, A Kozanecki, A Barcz, BJ Sealy and R Gwilliam, Implant isolation of both n-type InP and InGaAs by iron irradiation: effect of post annealing temperature, EDMO (2003), IEEE, pp18-23.
  3. BJ Sealy, Proton isolation revisited, III-Vs Review, 16 (2003) 36-38
  4. P Too, S Ahmed, R Gwilliam and B J Sealy, "Electrical isolation of n-type layers by helium implantation at variable substrate temperatures," NIM B188 (2002) 205-209.
  5. S Ahmed, B J Sealy, and R Gwilliam, "Dose dependence of proton-isolated n-type GaAs layers implanted at room temperature and 200ºC, Elect Letters, 38 (2002) 250-252.
  6. S Ahmed, R Gwilliam and B J Sealy, "Implant isolation in GaAs device technology: Effect of substrate temperature" NIM B188 (2002) 196-200.
  7. P. Too, S. Ahmed, B. J. Sealy, and R. Gwilliam, "Electrical characterization of Fe-doped semi-insulating InP after helium bombardment at different implant temperatures," Appl Phys Lett 80 (2002) 3745-3747.
  8. P Too, S Ahmed, C Jeynes, B J Sealy, and R Gwilliam, "Electrical isolation of n-type InP using MeV iron implantation at different doses and substrate temperatures," Elect Lett 38 (2002) 1225-1226.
  9. S Ahmed, J P Too Heng Kwee, B J Sealy and R M Gwilliam, "Proton implantation for effective electrical isolation of InP, InGaAs and GaAs: role of variable doses and implant temperature," Proc. 14th Conf Indium Phosphide and Related Materials. Piscataway, USA: IEEE, 2002, pp225-228.
  10. S C Subramaniam, A A Rezazadeh, J P Too Heng Kwee, S Ahmed, B J Sealy and R M Gwilliam, "Annealing characteristics of He+-ion implant isolation of InP/InGaAs HBT structures," Proc 14th Conf on Indium Phosphide and Related Materials. Piscataway, USA: IEEE, 2002, pp205-208.
  11. Ahmed S, Sealy BJ, Gwilliam RM.  Electrical isolation of n-type GaAs devices by MeV/MeV-like implantation of various ion species.  Proceedings EDMO, London, UK: IEEE, 2002, p18-23.
  12. Too Heng Kwee JP, Ahmed S, Sealy BJ, Gwilliam RM.  Comparison of two different isolation schemes for n-type InP by helium implantation, Proceedings EDMO. London, UK: IEEE, 2002, pp160-165.
  13. Ahmed S, Sealy BJ, Gwilliam RM.  Effect of proton implantation at variable temperatures and doses on the semi-insulating GaAs.  NIM B 206 (2003)1003-1007.
  14. M Webb, R Gwilliam, C Jeynes, S Donnelly, A Gandy, M-F Beaufort and BJ Sealy, Investigation into the implant parameters for smartcut in GaAs, PREP2004 April (2004)